全文获取类型
收费全文 | 28002篇 |
免费 | 3812篇 |
国内免费 | 2093篇 |
专业分类
化学 | 5593篇 |
晶体学 | 103篇 |
力学 | 4823篇 |
综合类 | 487篇 |
数学 | 10883篇 |
物理学 | 12018篇 |
出版年
2024年 | 32篇 |
2023年 | 326篇 |
2022年 | 583篇 |
2021年 | 769篇 |
2020年 | 934篇 |
2019年 | 768篇 |
2018年 | 740篇 |
2017年 | 1059篇 |
2016年 | 1234篇 |
2015年 | 889篇 |
2014年 | 1525篇 |
2013年 | 2213篇 |
2012年 | 1602篇 |
2011年 | 1888篇 |
2010年 | 1629篇 |
2009年 | 1944篇 |
2008年 | 1790篇 |
2007年 | 1791篇 |
2006年 | 1497篇 |
2005年 | 1331篇 |
2004年 | 1240篇 |
2003年 | 1031篇 |
2002年 | 976篇 |
2001年 | 783篇 |
2000年 | 669篇 |
1999年 | 598篇 |
1998年 | 553篇 |
1997年 | 405篇 |
1996年 | 351篇 |
1995年 | 359篇 |
1994年 | 328篇 |
1993年 | 274篇 |
1992年 | 246篇 |
1991年 | 189篇 |
1990年 | 167篇 |
1989年 | 128篇 |
1988年 | 121篇 |
1987年 | 133篇 |
1986年 | 109篇 |
1985年 | 129篇 |
1984年 | 131篇 |
1983年 | 72篇 |
1982年 | 96篇 |
1981年 | 62篇 |
1980年 | 31篇 |
1979年 | 37篇 |
1978年 | 29篇 |
1977年 | 29篇 |
1976年 | 15篇 |
1973年 | 22篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
71.
72.
《中国化学快报》2020,31(6):1415-1421
Electrocatalytic CO_2 reduction(CO_2 ER) into formate is a desirable route to achieve efficient transformation of CO_2 to value-added chemicals,however,it still suffers from limited catalytic activity and poor selectivity.Herein,we develop a hybrid electrocatalyst composed of bismuth and bismuth oxide nanoparticles(NPs) supported on nitrogen-doped reduced graphene oxide(Bi/Bi_2 O_3/NrGO) nanosheets prepared by a combined hydrothermal with calcination treatment.Thanks to the combination of undercoordinated sites and strong synergistic effect between Bi and Bi_2 O_3,Bi/Bi_2 O_3/NrGO-700 hybrid displays a promoted CO2 ER catalytic performance and selectivity for formate production,as featured by a small onset potential of-0.5 V,a high current density of-18 mA/cm~2,the maximum Faradaic efficiency of85% at-0.9 V,and a low Tafel slope of 166 mV/dec.Experimental results reveal that the higher CO_2 ER performance of Bi/Bi_2 O_3/NrGO-700 than that of Bi NPs supported on NrGO(Bi/NrGO) can be due to the partial reduction of Bi_2 O_3 NPs into Bi,which significantly increases undercoordinated active sites on Bi NPs surface,thus boosting its CO_2 ER performance.Furthermore,a two-electrode device with Ir/C anode and Bi/Bi_2 O_3/NrGO-700 cathode could be integrated with two alkaline batteries or a planar solar cell to achieve highly active water splitting and CO_2 ER. 相似文献
73.
Biophysical computational models are complementary to experiments and theories, providing powerful tools for the study of neurological diseases. The focus of this review is the dynamic modeling and control strategies of Parkinson's disease (PD). In previous studies, the development of parkinsonian network dynamics modeling has made great progress. Modeling mainly focuses on the cortex-thalamus-basal ganglia (CTBG) circuit and its sub-circuits, which helps to explore the dynamic behavior of the parkinsonian network, such as synchronization. Deep brain stimulation (DBS) is an effective strategy for the treatment of PD. At present, many studies are based on the side effects of the DBS. However, the translation from modeling results to clinical disease mitigation therapy still faces huge challenges. Here, we introduce the progress of DBS improvement. Its specific purpose is to develop novel DBS treatment methods, optimize the treatment effect of DBS for each patient, and focus on the study in closed-loop DBS. Our goal is to review the inspiration and insights gained by combining the system theory with these computational models to analyze neurodynamics and optimize DBS treatment. 相似文献
74.
随着电力需求的逐年增长,干式变压器的数量也在不断增加。干式变压器在运行时存在着振动和噪声的问题,为了对干式变压器振动的规律与特点进行研究,本文建立了干式变压器本体振动的有限元仿真模型,通过电磁分析获得相应的磁场分布,然后利用结构动力学分析得到其本体振动的相关规律。通过对处于运行状态的变压器振动数据进行实测分析,得到变压器振动的特征频率,然后对仿真结果进行对比分析,可以发现振动幅度与频率之间存在的关系。本文的研究结果可对干式变压器的减振降噪研究提供参考。 相似文献
75.
利用有效场理论研究了双模随机交错晶场中混合自旋 Blume-Capel 模型纳米管系统的重入现象, 发现了系统的重入现象与晶场取值概率、 晶场强度和外壳层与内壳层格点间最近邻交换相互作用的关系. 结果表明: 取值概率、 交换相互作用、 晶场强度和温度等诸多因素相互竞争, 使系统表现出丰富的磁化现象: 正( 负) 晶场较弱时, 系统只发生二级相变; 随着正( 负) 晶场增强, 系统的二级相变消失, 呈现一级相变; 一定条件下, 系统会出现重入现象. 相似文献
76.
Fines migration induced by injection of low-salinity water(LSW) into porous media can lead to severe pore plugging and consequent permeability reduction. The deepbed filtration(DBF) theory is used to model the aforementioned phenomenon, which allows us to predict the effluent concentration history and the distribution profile of entrapped particles. However, the previous models fail to consider the movement of the waterflood front. In this study, we derive a stochastic model for fines migration during LSW flooding, in which the Rankine-Hugoniot condition is used to calculate the concentration of detached particles behind and ahead of the moving water front. A downscaling procedure is developed to determine the evolution of pore-size distribution from the exact solution of a large-scale equation system. To validate the proposed model,the obtained exact solutions are used to treat the laboratory data of LSW flooding in artificial soil-packed columns. The tuning results show that the proposed model yields a considerably higher value of the coefficient of determination, compared with the previous models, indicating that the new model can successfully capture the effect of the moving water front on fines migration and precisely match the effluent history of the detached particles. 相似文献
77.
We derive a reduced-order model describing the inflation and deflation dynamics of a liquid-filled hyperelastic balloon, focusing on inviscid laminar flow and the extensional motion of the balloon. We initially study the flow and pressure fields for dictated motion of the solid, which throughout deflation are obtained by solving the potential problem. However, during inflation, flow separation creates a jet within the balloon, requiring a different approach. The analyses of both flow regimes lead to a simple piecewise model, describing the fluidic pressure during inflation and deflation, which is verified by finite element computations. We then use a variational approach to derive the equation describing the interaction between the extensional mode of the balloon and the entrapped fluid, yielding a nonlinear hybrid oscillator equation. Analytical and graphical investigations of the suggested model are presented, shedding light on its static and dynamic behaviour under different operating conditions. Our simplified model and its underlying assumptions are verified utilizing a fully coupled finite element scheme, showing excellent agreement. 相似文献
78.
Qiong-Tao Xie 《理论物理通讯》2020,72(6):65105-64
An analytical method is developed to study the two-mode quantum Rabi model. For certain specific parameter conditions, especially for the resonant conditions, we obtain an infinite number of the exact solutions of the eigenfunctions and associated energies. It is shown that there exist new types of the exact energies which do not correspond to the level-crossings. Our analytical method may find applications in some related models. 相似文献
79.
80.
混凝土是一种由粗骨料与水泥砂浆组成的非均质复合材料。本研究利用APDL语言程序编写三维水泥混凝土骨料随机投放程序并导入ABAQUS中,同时赋予各相材料塑性损伤本构关系来研究混凝土动态加载下的破坏规律,运用超声波在混凝土破碎中的作用机理对混凝土动态损伤破坏过程进行模拟研究。结果表明:随着超声动态载荷的增大,粗骨料体积分数为40%的混凝土始终能够承受最大应力载荷;随着超声应力波幅值增大,混凝土在动载荷下的损伤值逐渐增大,且粗骨料体积分数为40%时,其抗损伤能力最优;当粗骨料最大粒径逐渐增大,或者当粗骨料最小粒径增大,混凝土级配不合理导致性能不稳定,更易损伤破坏。 相似文献